- Journal of the Turkish Chemical Society Section A: Chemistry
- Vol: 8 Issue: 2
- 2-Naphthylthio Cyclotriphosphazene Derivatives: Synthesis, Characterization, Crystallographic and Fl...
2-Naphthylthio Cyclotriphosphazene Derivatives: Synthesis, Characterization, Crystallographic and Fluorescence Properties
Authors : Ceylan MUTLU BALCI
Pages : 535-552
Doi:10.18596/jotcsa.856600
View : 5 | Download : 2
Publication Date : 2021-05-31
Article Type : Research
Abstract :In this study, new cyclotriphosphazene derivatives bearing 2-naphthylthio group were reported. The reactions of hexachlorocyclotriphosphazene (1) with 2-naphthalenethiol (2) were carried out with NaH base in tetrahydrofuran solution under inert (Ar) atmosphere in (1:2), (1:4) and (1:6) molar ratios. As a result of the reactions, bis geminal (3), tetrakis (4) and hexakis (5) 2-naphthylthio substituted cyclotriphosphazene derivatives formed and isolated. These new compounds were characterized with elemental analysis, mass (MALDI-TOF) analysis, 31P{H} and 1H NMR spectroscopies. The molecular structure of compound 3 was illuminated by single-crystal X-Ray diffraction technique. Furthermore, the fluorescence properties of the newly designed and synthesis compounds (3-5) were examined.Keywords : Cylotriphosphazene, Crystal Structure, , Spectroscopy, Synthesis, X-Ray