- Journal of the Turkish Chemical Society Section A: Chemistry
- Vol: 3 Issue: 3 Special Issue
- N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERI...
N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION
Authors : Rukiye Fırıncı
Pages : 93-104
Doi:10.18596/jotcsa.90024
View : 4 | Download : 2
Publication Date : 2017-01-08
Article Type : Other
Abstract :A series of N-butyl substituted imidazolium salts, ( 1a-c ) and their pyridine enhanced precatalyst preparation stabilization and initiation ( PEPPSI ) themed palladium N -heterocyclic carbene complexes ( 2a-c ) were synthesized and characterized. Pd-NHC complexes were fully determined by elemental analysis and spectroscopic. The synthesized complexes were tested in Suzuki-Miyaura cross-coupling reaction. These complexes were found to be efficient catalysts for the Suzuki-Miyaura reaction of phenylboronic acid with aryl bromides.Keywords :