Kinetics of silver(I)-catalyzed oxidation of allyl alcohol by peroxodiphosphate in acetate buffers

Authors : Priyamvada Sharma, Riya Sailani, Deepmala Pareek, Chandra Lata Khandelwal

Pages : 158-169

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Publication Date : 9999-12-31

Article Type : Makaleler

Abstract :The kinetics and mechanism of silver(I)-catalyzed oxidation of allyl alcohol with peroxodiphosphate in acetate buffers have been studied. The rate is independent of allyl alcohol concentration. The effect of other reaction parameters such as hydrogen and acetate ions has also been studied. The rate law accounting for all experimental observations corresponds to the proposed mechanism. The energy and entropy of activation have also been evaluated by employing Eyring plots.
Keywords : Kinetics, mechanism, oxidation, allyl alcohol, peroxodiphosphate