Ag(I) complexes of benzimidazol-2-ylidene ligands: a study of catalytic efficiency towards three-component coupling reactions

Authors : Rafet Kilinçarslan, Naim Sadiç, Bekir Çetinkaya

Pages : 681-687

View : 18 | Download : 11

Publication Date : 9999-12-31

Article Type : Makaleler

Abstract :The $N$-heterocyclic carbene (NHC)--Ag(I) complexes 3a-c were synthesized from benzimidazolium chlorides (2a-c = NHC.HCl), incorporating benzyl derivatives and a 2-methoxyethyl group (a: $^{3}$N = 2,4,6-trimethylbenzyl; b: $^{3}$N = 2,3,5,6-tetramethylbenzyl; c: $^{3}$N = pentamethylbenzyl). The compounds were characterized by spectroscopic and elemental analyses. The synthesized NHC-Ag(I) complexes (3a-c) were tested as catalysts for the catalytic three-component coupling reaction of aldehyde, alkyne, and amine to propargylamines in various solvents. All complexes were active catalysts for catalytic three-component coupling reactions with good yields under neat and mild conditions (after 4 h, yields of up to 94%).
Keywords : $N$-heterocyclic carbene, benzimidazol-2-ylidene, coupling reaction, catalyst