Synthesis and Structural Characterization of the 2-[(o-pyridyl)-sulfanylmethyl]-pyrimidine-silver(I) Complex [Ag2(opsp)2](NO3)2

Authors : Li-rong Wen, Ming Li, Gui-long Znao, Xue-mei Li, Ou-yang Pingkai, Shu-sheng Zhang

Pages : 193-197

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Publication Date : 9999-12-31

Article Type : Makaleler

Abstract :The new silver(I) complexe [Ag2(opsp)2](NO3)2 (1) was synthesized by the self-assembly of AgX (X = NO3-) with the versatile multidentate ligand opsp (opsp = 2-[(o-pyridyl)-sulfanylmethyl]- pyrimidine). X-ray single-crystal diffraction analyses show that 1 is dinuclear molecule. In 1, 1 opsp ligand acts in a bidentate mode with 2 nitrogen atoms from a pyridine ring and a pyrimidine ring coordinating to 2 Ag(I) atoms, and the Ag(I) center is 2-coordinated by 2 nitrogen atoms showing linear coordination geometry.
Keywords : Multidentate ligand, Silver(I) complex, Crystal structure, Dinuclear molecule