- Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi
- Vol: 15 Issue: 3
- Zinc(II) and Cadmium(II) Salphen Catalyzed Alkylation Reactions to Form α-Alkylated Ketones
Zinc(II) and Cadmium(II) Salphen Catalyzed Alkylation Reactions to Form α-Alkylated Ketones
Authors : Salih Günnaz
Pages : 788-801
Doi:10.18185/erzifbed.1201394
View : 7 | Download : 3
Publication Date : 2022-12-30
Article Type : Research
Abstract :The zinc (II) and cadmium (II)-salphen catalyzed α-alkylation of ketones with primary alcohols is reported. Various α-alkylated ketones were obtained in good yields through a borrowing hydrogen strategy by using 1 % of catalysts and a catalytic amount of NaOH (10 mol%) as the base under air atmosphere. All synthesized compounds were characteized by 1H and 13C NMR.Keywords : Zinc, cadmium, salphen, alkylation, ketone