- Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi
- Vol: 23 Issue: 3
- Synthesis and Spectroscopic Properties of Newly Tetrapyrazinoporphyrazine Containing Gadolinium(III)...
Synthesis and Spectroscopic Properties of Newly Tetrapyrazinoporphyrazine Containing Gadolinium(III) Acetate
Authors : Mehmet Pişkin, Zafer Odabaş, Mahmut Durmuş
Pages : 602-607
Doi:10.35414/akufemubid.1180731
View : 25 | Download : 25
Publication Date : 2023-06-28
Article Type : Research Article
Abstract :A new tetrakis-(2-methylpyrazino)porphyrazinato gadolinium(III) acetate complex was synthesized. Elemental analysis, Fourier-Transform Infrared, Ultraviolet-visible, and fluorescence spectroscopy techniques clarified its structure. It can dissolve very well without aggregation in both Dimethyl sulfoxide and N, N-Dimethylformamide, which have high dielectric constant and high dipole moment from polar aprotic solvent type. Its aggregation property was also investigated in dimethyl sulfoxide at different concentrations, and it was determined to contain monomeric species. In addition, its fluorescence properties were investigated in Dimethyl sulfoxide and the effect of gadolinium(III) acetate metal ion as a heavy rare earth element was determined. According to the findings in this study, it may be used as an electronic and optical material and in various technological applications such as photocatalytic applications. In addition, these findings may be useful for systems that include changes in pyrazinoporphyrazine-like forms.Keywords : Tetrapirazinoporfirazin, Gadolinyum(III) asetat, Sentez, Agregasyon, Spektroskopi