- Communications Faculty of Sciences University Ankara Series B Chemistry and Chemical Engineering
- Vol: 27
- Interaction of Thorium Tetrachloride With Nitrogen and Oxygen Organic Donors
Interaction of Thorium Tetrachloride With Nitrogen and Oxygen Organic Donors
Authors : Margüerıte A. Wassef
Pages : 0-0
Doi:10.1501/Commub_0000000134
View : 8 | Download : 4
Publication Date : 1981-01-01
Article Type : Research
Abstract :Thorium tetrachloride reacts with organic compounds containing nitrogen or oxygen atom, to give cpmplex compounds of the type ThClj, nL, where n = 1, 1.5 or 2 and L = Djphenylp- hosphino ethane dioxide, diphenylphosphino mpthane dioxide, dimethyl-o-phenanthrolme, bipyridyl, dimethyl-bipyridyl, tripyridyl, pyridine N-oxide, dipyridyl amine and picolinic acid. Some öf these complexes contain coordinated water moleculeş. The reaction with triethyl phosp- hate gave the complex, Th ((EtO)2P02)4. 1 -No adducts have been obtained from the reaction of thorium tetrachloride with some or¬ganic phosphorus ligands. Infrâred spectra, thermal stability and conductivity of the formed coınplexes are discussed.Keywords : Interaction, Thorium Tetrachloride, Nitrogen