- Communications Faculty of Sciences University Ankara Series B Chemistry and Chemical Engineering
- Vol: 32 Issue: 01.02
- PREPARATION AND SPECTROSCOPIC INVESTIGATION OF MOLECULAR COMPLEXES OF SUBSTİTUTED ACE- TANILIDES WIT...
PREPARATION AND SPECTROSCOPIC INVESTIGATION OF MOLECULAR COMPLEXES OF SUBSTİTUTED ACE- TANILIDES WITH SOME TRINITROBENZENES
Authors : A. L. El-ansary
Pages : 76-86
Doi:10.1501/Commub_0000000284
View : 7 | Download : 4
Publication Date : 1986-01-01
Article Type : Research
Abstract :The solid molecular complexes formed betvveen substituted acetanilides and trinit- robenzenes are prepared and investigated by element analysis, IR and lH NMR spectroscopy. The results of element analysis confirm the formation of 1:1 complexes in a püre State. The spectral changes reveal that picric acid forms complexes with TT-K*, n-rc* electronic interac- tions and proton transfer while picrylchloride and trinitrobenzene result their complexes through K — K* and n - K* transitions. The results are confirmed bv NMRKeywords : The solid molecular complexes, analysis confirm the formation, . The results are confirmed