- Turkish Journal of Analytical Chemistry
- Vol: 5 Issue: 1
- Electroanalytical characterization of chloroquinoline substituted redox-active phthalocyanines
Electroanalytical characterization of chloroquinoline substituted redox-active phthalocyanines
Authors : Asiye Nas, Gülsev Dilber, Zekeriya Biyiklioğlu
Pages : 25-31
Doi:10.51435/turkjac.1307391
View : 21 | Download : 24
Publication Date : 2023-06-30
Article Type : Research Article
Abstract :In the first part of this study, the synthesis and characterization of organosoluble 5-chloroquinolin-8-yloxy substituted iron(II) (2) and oxo-titanium (IV) phthalocyanines (3) are reported for the first time. These compounds have been characterized by elemental analysis, Fourier transform infrared, electronic spectroscopy, and mass spectra. Electrochemical behaviors of metal-free and cobalt phthalocyanines and further new types of iron and oxo-titanium phthalocyanines were investigated using electroanalytical methods, such as cyclic (CV) and square wave voltammetry (SWV). According to the electrochemical results, phthalocyanines by and large showed one-electron metal- and/or ligand-based reversible or quasi-reversible reduction and oxidation processes. All in all, this study\'s results inevitably create a useful way to use them in possible future studies, which will particularly attempt to use the compound investigated in potential areas of use.Keywords : Iron, Titanium, Electrochemistry, Redox-active