- Turkish Journal of Chemistry
- Vol: 41 Issue: 4
- Singlet oxygen generation from poly[4-diacetoxyiodo]styrene and hydrogen peroxide
Singlet oxygen generation from poly[4-diacetoxyiodo]styrene and hydrogen peroxide
Authors : Mustafa Çatir
Pages : 467-475
View : 13 | Download : 9
Publication Date : 9999-12-31
Article Type : Makaleler
Abstract :Treatment of hydrogen peroxide with a polymer-supported hypervalent iodine compound, poly[4-diacetoxyiodo] styrene (PDAIS), generates singlet molecular oxygen ($^{1}$O$_{2})$. Singlet oxygen generation was proved by trapping with typical organic compounds such as conjugated dienes, aromatic dienes, and electron-rich alkene. When compared to monomer analogue, the use of PDAIS in peroxidation of substrates gave slightly better yields (45%-96%). Regeneration and reuse of PDAIS showed similar activity. The mechanism underlying generation of singlet oxygen and reaction scope was examined.Keywords : Hydrogen tetroxide, oxidation, peroxyiodane, polymer-supported hypervalent iodine, singlet oxygen