- Turkish Journal of Chemistry
- Vol: 40 Issue: 2
- Synthesis of novel chiral bisoxazoline ligands with a norbornadiene backbone: use in the copper-cata...
Synthesis of novel chiral bisoxazoline ligands with a norbornadiene backbone: use in the copper-catalyzed enantioselective Henry reaction
Authors : Rabia Delikuş, Emine Çakir, Nadir Demirel, Metin Balci, Betül Karataş
Pages : 248-261
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Publication Date : 9999-12-31
Article Type : Makaleler
Abstract :Novel chiral bisoxazoline ligands based on norbornadiene were synthesized and used for the asymmetric Henry reaction. Various aromatic aldehydes were converted into chiral $\beta $-nitro alcohols with high yields and moderate to acceptable enantioselectivities under the optimized reaction conditions.Keywords : Asymmetric synthesis, Henry reaction, chiral bisoxazolines, nitroaldol, copper