- Turkish Journal of Chemistry
- Vol: 23 Issue: 2
- An Investigation of the Formation Mechanism of Allene or Alkyne in the 6,7-Benzobicyclo[3.2.1]octane...
An Investigation of the Formation Mechanism of Allene or Alkyne in the 6,7-Benzobicyclo[3.2.1]octane System by Deuterium Labeling Experiments
Authors : Yavuz Taşkesenligil, Ferhan Tümer, Cavit Kazaz
Pages : 115-122
View : 13 | Download : 4
Publication Date : 9999-12-31
Article Type : Makaleler
Abstract :In order to reveal the real intermediate in the base-promoted reaction of 1, 3-bromo-4,4-dideuterio-6,7-benzobicyclo[3.2.1]octa-2,6-diene 10 was synthesized and its HBr elimination reaction studied. Reaction of 10 with potassium tert-butoxide yielded butoxyl ether 18 in which proton-deuterium exchange has occured.Keywords : Cyclic allene, Cyclic alkynes, Deuterium Labeling