- Turkish Journal of Chemistry
- Vol: 27 Issue: 3
- Crystal Structure of cis-bis(N,N-dimethyl-N'-benzoylthioureato)palladium(II)
Crystal Structure of cis-bis(N,N-dimethyl-N'-benzoylthioureato)palladium(II)
Authors : Göktürk Avşar, Hakan Arslan
Pages : 281-286
View : 9 | Download : 4
Publication Date : 9999-12-31
Article Type : Makaleler
Abstract :In this study cis-bis(N,N-dimethyl-N'-benzoylthioureato) palladium(II) is synthesised and the crystal structure is determined by X-ray diffraction methods. It crystallises in the space group P21/c, with a = 11.943(1) Å, b = 11.713(1) Å, c = 15.345(1) Å, b = 93.90(1)°, and Dcalc = 1.616 g cm-1 for Z = 4. The Pd(II) atom is in a four-coordinate geometry consisting of two thiocarbonyl S and two carbonyl O atoms from two ligand groups. The Pd-S and Pd-O bond lengths are 2.2313(6) and 2.0211(16) Å, respectively.Keywords : Complex, X-ray structure, single crystal, N, N-dimethyl-N'- benzoylthiourea