- Turkish Journal of Chemistry
- Vol: 28 Issue: 6
- Bromination of Tricyclo[7.2.1.02,7]dodeca-2,4,6,10-tetraene Derivatives: Electronic and Neighboring ...
Bromination of Tricyclo[7.2.1.02,7]dodeca-2,4,6,10-tetraene Derivatives: Electronic and Neighboring Group Effects on Bromination
Authors : Arif Daştan
Pages : 715-724
View : 10 | Download : 2
Publication Date : 9999-12-31
Article Type : Makaleler
Abstract :The bromination reaction of tricyclo[7.2.1.02,7]dodeca-2,4,6,10-tetraene derivatives was studied. The bromination of 9 gave only rearranged products 12 and 13, while the bromination of 8 with molecular bromine formed both rearranged 12 and non-rearranged products 15 and 16. The possible role of a substituent in the rearrangements was examined. All compounds were characterized properly, in particular by NMR spectra and chemical transformation.Keywords : Bromination, Wagner-Meerwein Rearrangement (W.M.R.), Polybromides, Neighboring Group Effect