- Turkish Journal of Chemistry
- Vol: 31 Issue: 4
- The Synthesis of 2-(Chloromethyl)-6-Hydroxy-2H-Pyran-3 (6H)-one via Achmatowicz Rearrangement
The Synthesis of 2-(Chloromethyl)-6-Hydroxy-2H-Pyran-3 (6H)-one via Achmatowicz Rearrangement
Authors : Zuhal Gerçek
Pages : 491-494
View : 11 | Download : 6
Publication Date : 9999-12-31
Article Type : Makaleler
Abstract :Achmatowicz rearrangement was carried out with 2-chloro-1-(furan-2-yl) ethanol, which was synthesized starting from 1-(furan-2-yl) ethanone. It was shown that the oxidation of 2-chloro-1-(furan-2-yl) ethanol with m-CPBA produced 2-(chloromethyl)-6-hydroxy-2H-pyran-3 (6H)-one in good yield (70%).Keywords : Oxidation, furan, 2-chloro-1-(furan-2-yl) ethanol, m-CPBA, rearrangement, pyranones