- Turkish Journal of Chemistry
- Vol: 32 Issue: 1
- Synthesis, X-ray Structure, and Bioassay of Newly Synthesized Trimethyltin(IV) 2,3-Methylenedioxy Be...
Synthesis, X-ray Structure, and Bioassay of Newly Synthesized Trimethyltin(IV) 2,3-Methylenedioxy Benzoate
Authors : Mukhtiar Hussain, Muhammad Hanif, Saqib Ali
Pages : 25-33
View : 11 | Download : 3
Publication Date : 9999-12-31
Article Type : Makaleler
Abstract :Trimethyltin(IV) complex containing the carboxylate ligand 2,3-methylenedioxybenzoic acid (HL) have been synthesized and characterized in solution state by multinuclear NMR (1H, 13C and 119Sn) using the noncoordinating solvent and also in solid sate by FTIR, mass spectrometry, and X-ray crystallography. Spectroscopic data have shown that methylenedioxy moiety has not coordinated with tin atom; instead, the coordination site is a -COO group, which is proved by spectral and XRD data. The solid state structure shows the trigonal bipyramidal geometry with a space group P21/c. This compound was tested for its in vitro antitumor activity.Keywords : 2, 3-methylenedioxybenzoic acid, spectroscopy, X-ray structure, antitumor activity