- Turkish Journal of Chemistry
- Vol: 34 Issue: 3
- Convenient synthesis of monomeric steroids from steroidal oxalate dimers using flash vacuum pyrolysi...
Convenient synthesis of monomeric steroids from steroidal oxalate dimers using flash vacuum pyrolysis (FVP)
Authors : Lutfun Nahar, Alan B. Turner And Satyajit D. Sarker
Pages : 359-366
Doi:10.3906/sag-1205-85
View : 10 | Download : 5
Publication Date : 9999-12-31
Article Type : Makaleler
Abstract :Flash vacuum pyrolysis (FVP) or thermolysis (FVT), an environmentally friendly method for studying organic reaction mechanisms as well as synthesis, was applied to a series of oxalate dimers (1, 3, 5, 7, 9, 11, 13, and 15) to synthesise monomeric enes, dienes, and a triene (2, 4, 6, 8, 10, 12, 14, and 16). All steroidal monomers were identified by spectroscopic means.Keywords : Steroid, oxalate dimers, steroidal alkene, diene, triene, FVP.