- Natural and Applied Sciences Journal
- Vol: 2 Issue: 1
- Photochemical Reaction of Metal Carbonyls [M(CO)6(M = Cr,Mo,W)] with 2-acetyl-5- chlorothiophenemeth...
Photochemical Reaction of Metal Carbonyls [M(CO)6(M = Cr,Mo,W)] with 2-acetyl-5- chlorothiophenemethanesulfonylhydrazone
Authors : Sema Sert
Pages : 27-31
Doi:10.38061/idunas.463196
View : 8 | Download : 4
Publication Date : 2019-06-30
Article Type : Research
Abstract :The new complexes, [M(CO) 5 (msh4)] (Cr(1), Mo(2), W(3)), have been synthesized by the photochemical reaction of metal carbonyls with 2-acetyl-5-chlorothiophenemethanesulfonylhydrazone( msh4 ) .The structure of these complexes has been investigated by using elemental analyses; FT-IR; EI-MS and 1 H NMR spectrometric methods. According to all spectroscopic data, msh4 is monodaentate and coordinate via thiophene ring sulfur.Keywords : Metal carbonyls, Methanesulfonylhydrazone, Photochemical Reactions.