- Natural and Applied Sciences Journal
- Vol: 1 Issue: 2
- Synthesis and Characterization of Metal Carbonyls [M(CO)6(M = Cr,Mo,W)] with Indole -3-carboxyaldehy...
Synthesis and Characterization of Metal Carbonyls [M(CO)6(M = Cr,Mo,W)] with Indole -3-carboxyaldehydemethanesulfonylhydrazone
Authors : Sema Sert
Pages : 31-34
Doi:10.38061/idunas.444281
View : 9 | Download : 4
Publication Date : 2018-12-29
Article Type : Research
Abstract :Abstract Four new complexes, M(CO) 5 (inmsh) (M=Cr(1), Mo(2),W(3)) and Re(CO) 4 Br(inmsh) (4), were synthesized by the photochemical reaction of metal carbonyls with indole-3-carboxyaldehydemethanesulfonyl hydrazone(inmsh) and characterized by using elemental analysis, 1 H NMR, LC-MS and IR spectra. The spectroscopic studies show that inmsh behaves as a monodantate ligand coordinating via imine N donor atom in [M(CO) 5 (inmsh)] (M=Cr, Mo, W) and Re(CO) 4 Br(inmsh).Keywords : Sulfonylhydrazones, Metal Carbonyls