- Journal of the Turkish Chemical Society Section A: Chemistry
- Vol: 5 Issue: 1
- THE LATEST ADVANCEMENTS IN THE ACYLATION REACTIONS VIA CROSS-DEHYDROGENATIVE COUPLING AND/OR METAL C...
THE LATEST ADVANCEMENTS IN THE ACYLATION REACTIONS VIA CROSS-DEHYDROGENATIVE COUPLING AND/OR METAL CATALYSTS
Authors : Soykan Ağar, Omer Tahir Gunkara
Pages : 247-268
Doi:10.18596/jotcsa.338292
View : 4 | Download : 2
Publication Date : 2017-09-01
Article Type : Other
Abstract :There are quite many examples in the scientific literature regarding the acylation reactions, especially the metal-catalyzed acylation reactions, metal-free acylation reactions, metal-catalyzed acylation via cross-dehydrogenative coupling (CDC) reactions and metal-free acylation via cross-dehydrogenative coupling (CDC) reactions. In this review paper, the most important examples of these domains were brought together and their mechanisms were exhibited in a clear, chronological format. Following these, the best example study towards green chemistry with a metal-free and high-yielding route was mentioned and discussed to demonstrate what has achieved in this field regarding the new acylation reaction mechanisms using the advantages of cross-dehydrogenative coupling (CDC) reactions. The most prominent studies regarding these domains have been examined thoroughly and the latest progress in this field was explained in detail.Keywords : Acylation, Cross-Dehydrogenative coupling (CDC) reactions, C-C bond formation, C-H bond activation, Metal Catalysts