- Sigma Mühendislik ve Fen Bilimleri Dergisi
- Vol: 34 Issue: 2
- SYNTHESIS AND THERMAL PROPERTIES OF NOVEL MALEONITRILES
SYNTHESIS AND THERMAL PROPERTIES OF NOVEL MALEONITRILES
Authors : Ali Erdoğmuş
Pages : 153-158
View : 8 | Download : 4
Publication Date : 2016-06-01
Article Type : Research
Abstract :In this study, the synthesis and thermal properties of two novel maleonitriles bearing 8-membered heterocyclic derivatives is described first time. New maleonitriles, benzo-(1,2-bis-methylthio)maleonitrile and [Benzo-15-crown-5]-(4,5-bis-methylthio)maleonitrile have been prepared by the reaction of different alkyl halides such as 1,2-bis(brommethyl)benzene and 4,5-bis-(brommethyl)[benzo-15-crown-5] with dithiomaleonitrile disodium salt. Both compounds are characterized by IR, Mass, NMR spectroscopy as well as elemental analysis.Keywords : Macrocycle, maleonitrile, crown ethers, thermal properties.