- Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi
- Vol: 26 Issue: 6
- 2,4,6-Tris(p-aminoanilino)-1,3,5-triazine: Synthesis and Electron Paramagnetic Resonance (EPR) Analy...
2,4,6-Tris(p-aminoanilino)-1,3,5-triazine: Synthesis and Electron Paramagnetic Resonance (EPR) Analysis
Authors : Özgül KARATAŞ, Yusuf CEYLAN, Ziya Erdem KOÇ
Pages : 1170-1179
Doi:10.16984/saufenbilder.1135112
View : 10 | Download : 2
Publication Date : 2022-12-31
Article Type : Research
Abstract :A significant group of compounds arise from substituted s-triazine derivatives that have tripodal heterocyclic compound. Compounds classified as heterocyclic possible created the largest and most diverse family of organic compounds. In this study, we reported that a new template has been syntheses from a cyanuric chloride and its diamine derivative. The desired triamine a tripodal 2, 4, 6-tris (p-aminoaanilino)-1, 3, 5-triazine (C21H21N9), called to be TRIPOD, has been obtained from cyanuric chloride with 3 eq of p-phenylenediamine reaction in acetone. After synthesis, TRIPOD sample which was polycrystal form was irradiated by cobalt-gamma source. The electron paramagnetic resonance spectra of TRIPOD were recorded using X-band EPR spectrometer at room temperature in three axes (x, y, z) which are perpendicular at 10 intervals. The EPR spectrum was simulated using computer program and by using the spectrum. The radical structure was determined in the sample.Keywords : EPR, Irradiation Effects, Radical, s-Triazine, Synthesis